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1 Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba,
Canada R3T 2N2
2 Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, Canada
R3T 2N2
* E-mail: frank_hawthorne{at}umanitoba.ca
A variety of mushroom tourmaline from the Kat Chay mine, Momeik, near
Mogok, Shan state, Myanmar, consists of a black-to-grey single-crystal core
from which a single prismatic crystal reaches to the edge of the mushroom,
forming a slight protuberance. The rest of the mushroom (
50% by volume)
consists of extremely acicular sub-parallel crystals that diverge toward the
edge of the mushroom. The acicular crystals are dominantly colourless to
white, with a continuous black zone (2 mm across) near the edge, and pale pink
outside the black zone. The composition varies from
Na0.75Ca0.05
(Li0.80Al0.70Fe1.10Mn0.30Ti0.10)Al6
Si6
(BO3)3O18(OH)3(OH,F) at the base
of the mushroom to
Na0.60Ca0.06
(Li1.00Al1.98Fe0.02)Al6
(Si5.35
B0.65)(BO3)3O18(OH)3
(OH,F) close to the edge at the top of the mushroom. The principal
substitutions are: (1) YLi + YAl
YFe* +
YFe* and (2) TB +
YAl
Si + YFe*, but
there are five other minor substitutions that are also operative. There are
six significant compositional discontinuities at textural boundaries in the
mushroom, suggesting that the changes in habit are driven in part by changes
in external variables such as T and P, plus possible
involvement of new fluid phases.
KEYWORDS: elbaite, tourmaline, electron microprobe analysis, zoning, Mogok, Myanmar
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