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Mineralogical Magazine; April 2005; v. 69; no. 2; p. 125-136; DOI: 10.1180/0026461056920240
© 2005 Mineralogical Society of Great Britain and Ireland
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Stability of naujakasite in hyperagpaitic melts, and the petrology of naujakasite lujavrite in the Ilímaussaq alkaline complex, South Greenland

T. Andersen1,* and H. Sørensen2

1 Department of Geosciences, University of Oslo, P.O. Box 1047 Blindern, N-0654 Oslo, Norway
2 Geological Institute, Copenhagen University, Øster Voldgade 10, DK-1350 København K, Denmark

* E-mail: tom.andersen{at}geo.uio.no

Naujakasite (Na6(Fe,Mn)Al4Si8O26) is a characteristic, rock-forming mineral of hyperagpaitic naujakasite lujavrite (arfvedsonite + naujakasite + steenstrupine + albite ± relict nepheline ± microcline ± ussingite) from the Ilímaussaq complex, South Greenland, and is only known from this complex. The qualitative stability relationships of naujakasite-bearing, low-variance liquidus mineral assemblages at near-solidus conditions in lujavritic magma can be modelled within the six-component system Si-Al-Fe-Na-O-H. The modelling suggests that an uncommon combination of elevated water activity and low oxygen fugacity is needed to stabilize arfvedsonite + naujakasite mineral assemblages in highly sodic liquids. These conditions are incompatible with the stable coexistence of aegirine and arfvedsonite. They are met in the arfvedsonite-bearing lujavrites of Ilímaussaq, but apparently not in rocks of similar composition in the Khibina and Lovozero complexes, Kola Peninsula, where aegirine- or aegirine-arfvedsonite-bearing mineral assemblages are characteristic. Liquid lines of descent leading to crystallization of naujakasite have to pass through the albite+nepheline+arfvedsonite liquidus field in the Si-Al-Fe-Na-O-H system, reaching this field at the high-Na side of the albite-nepheline-arfvedsonite plane.

KEYWORDS: nepheline syenite, agpaitic rocks, naujakasite, water activity, oxygen fugacity, Ilímaussaq complex, Greenland







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