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The formation-dissolution-precipitation cycle of melanterite at the abandoned pyrite mine of Genna Luas in Sardinia, Italy: environmental implications

Dipartimento di Scienze della Terra, Università di Cagliari, Via Trentino 51, I-09127 Cagliari, Italy

^* E-mail: frauf{at}unica.it

At the abandoned pyrite mine at Genna Luas (Sardinia, Italy), melanterite is the most environmentally important secondary phase associated with pyrite oxidation. A complete cycle, including formation on pyrite surface, dissolution in water, precipitation from water and subsequent alteration, can be observed. The oxidation of pyrite to melanterite is related mainly to the ‘intrinsic’ features of the Genna Luas pyrite, such as its cryptocrystalline pseudo-colloidal texture. During melanterite formation on pyrite there is transient storage of Fe²⁺, SO^2–₄and acidity. This is controlled mainly by wetting-drying seasonal cycles. Laboratory experiments have shown that the simple dissolution of melanterite is an acidity-generating process which affects the geochemistry of water and, indirectly, contributes to the supply of the Fe³⁺ required for the aqueous oxidation of pyrite. According to this geochemical model, the interaction between rainwaters and ground pyritic materials accumulated in heaps generates hyperacidic saline waters (pH = 0.6; TDS = 300 g/l) with very high SO₄ ^2– contents (203 g/l), Fe²⁺ contents (73 g/l), Zn contents (11 g/l), and numerous potentially toxic elements. Melanterite precipitates from these waters (SI_Melanterite = 0.15, calculated using PHRQPITZ software), giving rise to attractive emerald green crystal aggregates which, when exposed to air, alter to a fine white powder composed mainly of melanterite, and minor amounts of rozenite and szomolnokite.

KEYWORDS: melanterite, pyrite oxidation, hyperacidic waters, environmental geochemistry, Genna Luas mine-site, Sardinia, Italy

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