On the complex zonality in grandite garnets and implications

Saint Petersburg State University, Department of Crystallography, Saint Petersburg, Russian Federation

The available data on compositional zoning in grossular-andradite (grandite) garnets occurring at different scales, mainly due to the variations of their Fe (super 3+) /Al ratios, and the hypotheses on the origin of this zoning are reviewed. Four zoned crystals of grandites showing different optical properties have been studied by means of X-ray diffraction. Optical and structural studies suggest three superimposed scales of Fe (super 3+) /Al zonality along [110]. The drastic change of the structural characteristics from sample to sample correlates with the change of their optical patterns. The superfine oscillatory zoning has been described in terms of irregular interstratified structures with a high degree of segregation. The self-affinity of zoning at different scales testify to the possible origin of the zonality due to the non-linear dynamics at the growth front. The wide variation of the layer compositions revealed by the modelling of the X-ray diffraction profiles seems to contradict the hypothesis of unmixing in grandite garnets.

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