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Mineralogical Magazine; October 1997; v. 61; no. 5; p. 677-683
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Crystal structure of austinite, CaZn(AsO 4 )OH

Lori A. Clark, Joseph J. Pluth, Ian Steele, Joseph V. Smith, and Stephen R. Sutton

University of Chicago, Department of Geophysical Sciences, Chicago, IL, United States

Austinite belongs to the adelite mineral group of calcium and lead arsenates, and has the conichalcite/descloizite type of crystal structure. The crystal structure of nearly pure austinite, CaZn(AsO 4 )OH, was redetermined (R = 0.014) and the absolute configuration identified. The space group P2 1 2 1 2 1 and cell parameters a 7.5092(8), b 9.0438(9), c 5.9343(8) Aa match previous data. Zinc octahedra share edges to form chains parallel to c. Arsenic tetrahedra share vertices with the Zn octahedra to generate a compact framework. Calcium square antiprisms share edges to make chains parallel to a that occupy the channels in the zinc-arsenic framework.

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B. J. Reddy, R. L. Frost, and W. N. Martens
Characterization of conichalcite by SEM, FTIR, Raman and electronic reflectance spectroscopy
Mineralogical Magazine, April 1, 2005; 69(2): 155 - 167.
[Abstract] [Full Text] [PDF]




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