FIG. 1. The cuprobismutite series and related pad
raite, according to (a) Makovicky (1989) and (b) Mumme (1986). Pad
raite shares the common Cu8Bi8S16 layer with members of the cuprobismutite series. In the pad
raite structure (b, right), the D module has variable thickness along the c axis: either one octahedron thick at the T contact, or two octahedra thick along the trigonal-tetrahedral match. In each drawing, atoms are, in decreasing size, S, Bi and Cu. In the drawings for pad
raite, the order is Pb, S, Bi, Ag and Cu.